Head to Head
| Spain Primera Women | 2023/01/28 11:00 | Villarreal (W) v CD Alaves (W) | W | 1-0 |
| Spain Primera Women | 2022/10/01 10:00 | CD Alaves (W) v Villarreal (W) | W | 0-4 |
| Spain Primera Women | 2022/01/08 11:00 | Villarreal (W) v CD Alaves (W) | W | 3-1 |
| Spain Primera Women | 2021/09/25 15:00 | CD Alaves (W) v Villarreal (W) | L | 2-0 |