Head to Head
| Spain Primera Women | 2023/01/28 11:00 | Villarreal (W) v CD Alaves (W) | W | 1-0 |
| Spain Primera Women | 2022/10/01 10:00 | CD Alaves (W) v Villarreal (W) | W | 0-4 |
| Spain Primera Women | 2022/01/08 11:00 | Villarreal (W) v CD Alaves (W) | W | 3-1 |
| Spain Primera Women | 2021/09/25 15:00 | CD Alaves (W) v Villarreal (W) | L | 2-0 |
Home History
| Spain Primera Women | 2024/06/15 10:00 | Atletico Madrid (W) v Villarreal (W) | L | 1-0 |
| Spain Primera Women | 2024/06/09 18:30 | Villarreal (W) v Sporting De Huelva (W) | W | 2-0 |
| Spain Primera Women | 2024/05/25 10:00 | Levante UD (W) v Villarreal (W) | L | 2-1 |
| Spain Primera Women | 2024/05/10 16:30 | Villarreal (W) v Eibar (W) | D | 1-1 |
| Spain Primera Women | 2024/05/04 16:00 | Athletic Bilbao (W) v Villarreal (W) | L | 1-0 |
| Spain Primera Women | 2024/04/27 10:00 | Villarreal (W) v Granada (W) | L | 1-2 |
| Spain Primera Women | 2024/04/21 12:00 | Villarreal (W) v Sevilla (W) | L | 1-2 |
| Spain Primera Women | 2024/04/13 16:30 | Barcelona (W) v Villarreal (W) | L | 5-1 |
Away History
| Spain Primera Federacion Women | 2024/04/27 17:30 | Alhama CF (W) v CD Alaves (W) | L | 2-1 |
| Spain Primera Federacion Women | 2024/04/21 10:00 | CD Alaves (W) v CE Europa (W) | W | 4-0 |
| Spain Primera Federacion Women | 2024/03/30 11:30 | CD Alaves (W) v Espanyol (W) | D | 0-0 |
| Spain Primera Federacion Women | 2024/03/23 11:00 | Cacereno (W) v CD Alaves (W) | L | 2-0 |
| Spain Primera Federacion Women | 2024/03/16 11:30 | CD Alaves (W) v SE AEM (W) | D | 1-1 |
| Spain Primera Federacion Women | 2024/02/17 12:00 | CD Alaves (W) v Deportivo La Coruna (W) | L | 0-2 |
| Spain Primera Federacion Women | 2024/02/10 15:00 | Fundacion Albacete (W) v CD Alaves (W) | W | 1-2 |
| Spain Primera Federacion Women | 2024/02/04 10:30 | CD Alaves (W) v Barcelona (W) B | L | 0-1 |