[1] Olympiakos 2-1 Volos NFC [7] 2021-09-23 07:00
Stadium: Karaiskakis Stadium Round: 11
Referee: Aristomenis Koutsiaftis Home Manager: Pedro Martins Away Manager: Guillermo Abascal
Head to Head
| Greece Super League 1 | 2021/03/01 17:30 | Volos NFC v Olympiacos | W | 1-2 |
| Greece Super League 1 | 2020/12/05 17:30 | Olympiacos v Volos NFC | W | 4-1 |
| Greece Super League 1 | 2019/12/22 15:15 | Volos NFC v Olympiacos | D | 0-0 |
| Greece Super League 1 | 2019/09/14 18:30 | Olympiacos v Volos NFC | W | 5-0 |
Home History
| Greece Super League 1 | 2021/09/22 15:15 | Olympiacos v Apollon Smyrnis | W | 4-1 |
| Greece Super League 1 | 2021/09/19 17:30 | Lamia v Olympiacos | W | 1-2 |
| UEFA Europa League | 2021/09/16 19:00 | Olympiacos v Antwerp | W | 2-1 |
| Greece Super League 1 | 2021/09/12 17:30 | Olympiacos v Atromitos Athinon | D | 0-0 |
| Europe Friendlies | 2021/09/03 17:00 | Aris Salonika v Olympiacos | D | 1-1 |
| UEFA Europa League Qualifying | 2021/08/26 18:45 | Slovan Bratislava v Olympiacos | D | 2-2 |
| UEFA Europa League Qualifying | 2021/08/19 19:00 | Olympiacos v Slovan Bratislava | W | 3-0 |
| UEFA Champions League Qualifying | 2021/08/10 18:00 | Ludogorets Razgrad v Olympiacos | L | 6-3 |
Away History
| Greece Super League 1 | 2021/09/19 13:00 | Apollon Smyrnis v Volos NFC | W | 1-3 |
| Greece Super League 1 | 2021/09/12 15:15 | Volos NFC v Lamia | W | 2-1 |
| Europe Friendlies | 2021/09/04 16:00 | Volos NFC v Niki Volou | W | 2-0 |
| Europe Friendlies | 2021/08/29 16:00 | Volos NFC v AEK Athens | W | 4-3 |
| Europe Friendlies | 2021/08/14 17:00 | Aris Salonika v Volos NFC | L | 4-3 |
| Europe Friendlies | 2021/08/08 18:00 | Volos NFC v OFI Crete | W | 2-1 |
| Europe Friendlies | 2021/08/03 16:48 | Panaitolikos Argos v Volos NFC | W | 0-1 |
| Europe Friendlies | 2021/07/24 16:00 | FC Utrecht v Volos NFC | L | 6-2 |