Head to Head
| Italy Serie A Women | 2025/04/13 13:00 | Napoli (W) v Sassuolo (W) | L | 0-1 |
| Italy Serie A Women | 2025/03/02 11:30 | Sassuolo (W) v Napoli (W) | L | 3-1 |
| Italy Serie A Women | 2024/12/07 11:30 | Sassuolo (W) v Napoli (W) | L | 2-1 |
| Italy Serie A Women | 2024/09/20 12:30 | Napoli (W) v Sassuolo (W) | W | 1-0 |
| Italy Serie A Women | 2024/02/03 11:30 | Sassuolo (W) v Napoli (W) | L | 2-0 |
| Italy Serie A Women | 2023/11/05 14:00 | Napoli (W) v Sassuolo (W) | L | 0-1 |
| Italy Serie A Women | 2022/04/24 12:30 | Sassuolo (W) v Napoli (W) | D | 0-0 |
| Italy Serie A Women | 2021/11/13 13:30 | Napoli (W) v Sassuolo (W) | L | 0-1 |
Home History
| Coppa Italia Women | 2025/09/20 12:30 | Venezia Women v Napoli (W) | W | 1-5 |
| Coppa Italia Women | 2025/09/13 10:30 | Juventus (W) v Napoli (W) | L | 4-0 |
| Italy Serie A Cup Women | 2025/09/07 13:00 | Napoli (W) v Parma (W) | D | 2-2 |
| Italy Serie A Cup Women | 2025/08/23 18:30 | Lazio (W) v Napoli (W) | L | 2-1 |
| Italy Serie A Women | 2025/05/11 10:30 | Como (W) v Napoli (W) | L | 3-1 |
| Italy Serie A Women | 2025/04/27 10:30 | Napoli (W) v Sampdoria Women | W | 2-1 |
| Italy Serie A Women | 2025/04/18 17:30 | Lazio (W) v Napoli (W) | L | 2-1 |
| Italy Serie A Women | 2025/04/13 13:00 | Napoli (W) v Sassuolo (W) | L | 0-1 |
Away History
| Italy Serie A Cup Women | 2025/09/14 13:00 | Roma (W) v Sassuolo (W) | L | 3-0 |
| Italy Serie A Cup Women | 2025/09/07 15:30 | Sassuolo (W) v Ternana (W) | D | 1-1 |
| Italy Serie A Cup Women | 2025/08/24 18:30 | AC Milan (W) v Sassuolo (W) | W | 0-2 |
| Italy Serie A Women | 2025/05/11 10:30 | Sassuolo (W) v Sampdoria Women | W | 4-2 |
| Italy Serie A Women | 2025/05/03 13:00 | Lazio (W) v Sassuolo (W) | L | 5-0 |
| Italy Serie A Women | 2025/04/19 10:30 | Sassuolo (W) v Como (W) | W | 3-0 |
| Italy Serie A Women | 2025/04/13 13:00 | Napoli (W) v Sassuolo (W) | W | 0-1 |
| Italy Serie A Women | 2025/03/30 13:00 | Sampdoria Women v Sassuolo (W) | W | 2-5 |